Stabilization by the electron-accepting boron compounds. Anionic M0 complexes (M=group 10 metals) have attracted interest due to their potential as active catalysts for chemical reactions. Despite this, the determination of their molecular structures has been a rarity, primarily due to their extr
Extremely unstable anionic Pt complexes have been successfully stabilized by leveraging the electron-accepting ability of boron compounds. Credit: Hajime Kameo, OMUcomplexes have attracted interest due to their potential as active catalysts for chemical reactions. Despite this, the determination of their molecular structures has been a rarity, primarily due to their extremely high reactivity. This holds particularly true for Ptcomplexes, which are anticipated to be highly reactive.
Associate Professor Hajime Kameo, and Professor Hiroyuki Matsuzaka from the Osaka Metropolitan University Graduate School of Science and CNRS Senior Researcher Didier Bourissou elucidated the molecular structures of anionic Ptcomplexes by the electron-accepting properties of boron compounds. “Although platinum complexes that exhibit a variety of catalytic activities have been actively studied, anionic Ptcomplexes have remained a mystery,” stated Professor Kameo. “The results of this research not only enable us to elucidate the properties and functions of highly active chemicalbut also provide new guidelines for their creation. It is expected to lead to the development of innovative catalytic reactions mediated by these chemical species.”Complexes” by Dr.
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