Extreme redox variations in a superdeep diamond from a subducted slab - Nature

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Extreme redox variations in a superdeep diamond from a subducted slab - Nature
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Nature research paper: Extreme redox variations in a superdeep diamond from a subducted slab

The introduction of volatile-rich subducting slabs to the mantle may locally generate large redox gradients, affecting phase stability, element partitioning and volatile speciation. Here we investigate the redox conditions of the deep mantle recorded in inclusions in a diamond from Kankan, Guinea. Enstatite , ferropericlase and a uniquely Mg-rich olivine inclusion indicate formation in highly variable redox conditions near the 660 km seismic discontinuity.

We propose a model involving dehydration, rehydration and dehydration in the underside of a warming slab at the transition zone–lower mantle boundary. Fluid liberated by dehydration in a crumpled slab, driven by heating from the lower mantle, ascends into the cooler interior of the slab, where the HO is sequestered in new hydrous minerals. Consequent fractionation of the remaining fluid produces extremely reducing conditions, forming Mg-end-member ringwoodite.

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